How this calculator works
- Step 1pH−log₁₀[H₃O⁺]Lower means more acidic.
- Step 2WaterpH + pOH = 14At 25 °C.
- Step 3Back10^(−pH)Concentration from pH.
pH is the negative logarithm of the hydronium ion concentration. Because it is a logarithm, each step of 1 is a tenfold change.
In water at 25 °C the hydronium and hydroxide concentrations multiply to 1.0 × 10⁻¹⁴, so pH and pOH always add to 14.
Worked example: OpenStax Example 14.4
- pH
−log₁₀[H₃O⁺]
- log₁₀(1.2 × 10⁻³)−2.92
- pH2.92
- pOH14 − 2.9211.08
- [OH⁻]8.33 × 10⁻¹² M
Read the result
- pH 7.35.01 × 10⁻⁸ MSlightly basic: OpenStax Example 14.5.
- 0.0125 M KOHpH 12.10pOH 1.903: OpenStax Example 14.6.
Pure water at 25 °C has pH 7.00, with [H₃O⁺] and [OH⁻] both 1.00 × 10⁻⁷ M.
Assumptions and limits
- 25 °CpK_w changes with temperature.
- DiluteConcentration stands in for activity.
- No equilibriaWeak acids need Ka first.
- LogarithmicOne pH unit is a factor of 10.
Related chemistry tools
pH is a logarithm of concentration, so each step of one is a tenfold change.
To find the concentration first, use the molarity calculator. The log calculator shows the logarithm behind every pH value.
Common mistakes
Mistake: Using the acid’s concentration for a weak acid.
Instead: Work out [H₃O⁺] from Ka first.
Mistake: Thinking pH 4 is twice as acidic as pH 8.
Instead: It has 10,000 times more hydronium.
Checking the method
A separate script recomputes every value with 40-digit decimal logarithms and reproduces OpenStax Examples 14.4 to 14.6.
Read how we test our calculators, or browse more maths calculators.